基于纳米压痕和XRD-EPMA技术的超临界CO2注入煤体力学损伤演化机制

Study on the mechanical damage evolution mechanism of coal injected with supercritical CO2 using Nanoindentation and XRD-EPMA technology

  • 摘要: CO2地质封存技术是实现碳减排和废弃矿井资源再利用的有效技术之一,为揭示注入过程中超临界CO2与煤体的相互作用机制及对煤体力学性质的影响规律,利用纳米压痕、XRD、SPM及EPMA综合表征技术,研究了深部煤层ScCO2封存条件下煤体表面形貌、矿物组分及微观力学性能随溶浸时间的变化规律,分析了煤体力学损伤与CO2矿化反应的关联机制。结果表明:ScCO2具有溶剂特性,会与煤体发生溶蚀作用,碳酸盐和硫酸盐相比于硅酸盐具有更高的溶解度和溶解速率,随着浸泡时间的增加,煤中碳酸盐和硫酸盐矿物含量缓慢持续减少。ScCO2溶浸显著改变了煤体微观力学性质,弹性模量和硬度均随ScCO2溶浸作用时间的增加呈指数下降趋势,弹性模量降至原煤的85.71%~90.33%,硬度降至76.07%~84.70%,其中溶浸2 d后煤体弹性模量和硬度值衰减最为显著,分别下降超过86.9%和81.2%。由于溶浸过程中部分矿物质被溶解,导致煤体矿物种类和分布较为均一稳定,煤样力学性质均质性增强。在ScCO2溶浸过程中,煤逐渐由弹性变形转变为塑性变形,纳米压痕裂纹迅速拓展,煤表面微观形貌损伤严重,蠕变变形量线性增加。溶蚀反应对煤体孔隙结构的改变和煤体弹−塑性的转变,增强了纳米压痕载荷曲线的离散性,造成弹出事件发生频率增加。研究可为煤层气增产开发、深部煤层CO2储存安全性评估提供科学依据。

     

    Abstract: CO2 geological storage technology is one of the effective technologies for achieving carbon reduction and the reuse of abandoned mine resources. In order to reveal the interaction mechanism between supercritical CO2 and coal during injection and its impact on the mechanical properties of coal, comprehensive characterization techniques such as nanoindentation, XRD, SPM, and EPMA were used to study the changes in coal surface morphology, mineral composition, and micro mechanical properties with leaching time under ScCO2 storage conditions in deep coal seams. The correlation mechanism between coal mechanical damage and CO2 mineralization reaction was analyzed. The results indicate that ScCO2 has solvent properties and can undergo dissolution with coal. Carbonates and sulfates have higher solubility and dissolution rates compared to silicates. As the soaking time increases, the content of carbonate and sulfate minerals in coal slowly and continuously decreases. ScCO2 leaching significantly changed the micro mechanical properties of coal, with both elastic modulus and hardness showing an exponential decrease trend with increasing ScCO2 leaching time. The elastic modulus decreased to 85.71%−90.33% of the original coal, and the hardness decreased to 76.07%−84.70%. Among them, after 2 days of leaching, the elastic modulus and hardness values of coal decreased the most significantly, with a decrease of over 86.9% and 81.2%, respectively. Due to the dissolution of some minerals during the leaching process, the types and distribution of minerals in the coal body are relatively uniform and stable, and the mechanical properties of the coal sample are more homogeneous. In the process of ScCO2 solution leaching, the coal gradually changes from elastic deformation to plastic deformation, the nano indentation crack expands rapidly, the micro morphology of the coal surface is seriously damaged, and the creep deformation increases linearly. The dissolution reaction changes the pore structure and elastic-plastic transformation of coal, enhancing the discreteness of the nanoindentation load curve and causing an increase in the frequency of popping events. The study can provide scientific basis for the development of coalbed methane production and the safety assessment of CO2 storage in deep coal seams.

     

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