高温热源热辐射驱动周围煤体燃烧的作用机制与定量表征

Mechanisms and quantitative characterization of surrounding coal combustion driven by thermal radiation from a high-temperature source

  • 摘要: 为探究高温热源产生的热辐射对周围煤体燃烧的作用机制并实现其影响的定量表征,通过高温热源定量热辐射实验、理论建模与数值模拟方法,系统揭示了热辐射驱动煤燃烧是一个主导性驱动与级联放大的过程。结果表明:热辐射通量是主导煤燃烧过程的关键外部因素,它不仅决定氧化反应路径,更显著加速了煤氧化燃烧各个阶段的演化进程。将热辐射作用下的煤燃烧过程划分为4个连续演化阶段:水分蒸发阶段(Ⅰ)、自维持氧化阶段(Ⅱ)、热分解与剧烈氧化阶段(Ⅲ)以及碳氧化阶段(Ⅳ)。在较低热辐射通量条件下,氧化反应主要依赖煤氧自热,小粒径煤因比表面积大、堆积致密,更易在自维持氧化阶段(Ⅱ)实现热量积累;而在较高热辐射通量作用下,外部热辐射能直接驱动煤体发生完全氧化,显著加快了从水分蒸发阶段(Ⅰ)到自维持氧化阶段(Ⅱ),进而向热分解与剧烈氧化阶段(Ⅲ)的关键转变。基于能量守恒原理与CO突变点温度,研究建立了临界热辐射通量计算模型。该模型表明,临界热辐射通量qcri随粒径减小显著降低,进一步证实在热辐射作用下小粒径煤更易跨越氧化燃烧各阶段的关键节点。通过CH4/CO混合气体燃烧模拟,从反应动力学角度阐明,高温热源对煤燃烧伴生气体燃烧的驱动源于对自由基网络与基元反应速率的定量调控。高温显著促进了以H和O为代表的链分支自由基的生成,促使CH4的消耗路径向H自由基主导的脱氢反应倾斜,同时抑制了CO向CO2的转化。该微观尺度上的反应速率再分配有效加速了燃料消耗与中间产物积累,导致燃烧中心前移、整体反应强度显著增强,从而驱动煤体燃烧由阶段(Ⅲ)向更剧烈的燃烧状态转变。

     

    Abstract: To investigate the mechanism by which thermal radiation from high-temperature sources influences the combustion of surrounding coal and to quantitatively characterize its impact, a combined approach integrating quantitative thermal radiation experiments, theoretical modeling, and numerical simulations are employed. Thermal radiation-driven coal combustion is systematically revealed as the dominant driving process, exhibiting cascading amplification effects. The results indicate that thermal radiation flux is a crucial external factor governing the coal combustion process. It influences not only the oxidation reaction pathways but also significantly accelerates the evolution across all stages of coal oxidation and combustion. The coal combustion process under thermal radiation is divided into four consecutive stages: moisture evaporation (Ⅰ), self-sustained oxidation (Ⅱ), thermal decomposition and intense oxidation (Ⅲ), and carbon oxidation (Ⅳ). Under low thermal radiation flux conditions, oxidation reactions primarily depend on coal-oxygen self-heating, with smaller particle sizes enhancing heat accumulation during the self-sustained oxidation stage (Ⅱ) due to their larger specific surface area and denser packing. In contrast, under higher thermal radiation flux conditions, external thermal radiation directly drives complete oxidation on the coal surface, markedly accelerating the critical transitions from the moisture evaporation stage (Ⅰ) to the self-sustained oxidation stage (Ⅱ) and subsequently to the thermal decomposition and intense oxidation stage (Ⅲ). Based on the principle of energy conservation and the temperature at the point of abrupt change in CO, a model for calculating the critical thermal radiation flux was established. This model demonstrates that the critical thermal radiation flux qcri significantly decreases as particle size diminishes, further confirming that coal with smaller particle sizes can more easily navigate the key transition points of each oxidation combustion stage under thermal radiation. Through simulations of CH4/CO mixed gas combustion and from the perspective of reaction kinetics, the influence of a high-temperature source on the combustion of coal-derived gases is attributed to its quantitative modulation of the radical pool and the rates of elementary reactions. High temperatures significantly promote the generation of chain-branching radicals, such as H and O, shifting the CH4 consumption pathway toward H radical-dominated dehydrogenation while suppressing the conversion of CO to CO2. This redistribution of reaction rates at the micro-scale effectively accelerates fuel consumption and intermediate product accumulation, resulting in a forward shift of the combustion center and a notable enhancement in overall reaction intensity, thereby driving the transition from stage (Ⅲ) to a more intense combustion state.

     

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